MONOLAYER POLYMER PHOTOCELLS. THE OPPORTUNITIES

Authors

  • Duško Dudić Department of Chemistry, University of the Free State, Private Bag X13, Phuthaditjhaba, 9866 South Africa Vinča Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, 11001 Belgrade, Serbia
  • Adriaan S. Luyt Center for Advanced Materials, Qatar University, PO Box 2713, Doha, Qatar

DOI:

https://doi.org/10.7251/cm.v2i6.4079

Abstract

The conversion of solar energy into electricity is in the focus of a large number of scientists. Because of the problems caused by the use of fossil fuels, the use of renewable and environmentally friendly energy sources is desirable, and in some countries the use of a certain percentage of such energy sources becomes a legal obligation. Today there are commercially available silicon solar cells with prices ranging from 800 USD/kW (about 10 m2/kW) and efficiency in the range of 10-20%. The main obstacle to a wide use of these energy sources is the high price of such generated electric power in comparison to the costs of electricity from classical sources (hydro, thermal and nuclear power plants). Technological progress has been made in the development of polymer-based organic photovoltaic (OPV) solar cells, and their energy efficiency is approaching the value of 10%, whereas the price per unit of output can be significantly lower than silicon solar cells. A shortcoming of OPV solar cells is their short life, and that is why they did not find a wider application. A single-layer polymer photovoltaic is characterized by a simple design and potentially very low production cost. It can be assumed that because of these properties, the polymer monolayer photocell can become a cheap substitute for widespread photocells based on classic semiconductors. In this article, the existing published achievements in the development of a monolayer polymer solar cell аre presented, and also the original solutions that are the result of investigations conducted by the authors

References

F. Dimroth, et all., Wafer bonded four-junction GaInP/GaAs/GaInAsP/GaInAs concentrator solar cells with 44.7% efficienc, Progress in Photovoltaics, Vol. 22−3 (2014) S.277−282

B. O’Regan, M. Grätzel, A low-cost, high-efficiency solar-cell based on dye sensitized colloidal TiO2 films, Nature, Vol. 353 (1991) 737–40.

S. Mathew, A. Yella, P. Gao, R. H. Baker, B. F. E. Curchod, N. A. Ashtani, I. Tavernelli, U. Rothlisberger, M. K. Nazeeruddin, M. Gratzel, Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers, Nature Chemistry, Vol. 6 (2014) 242−247.

P. Atkins, J. de Paula, Physical Chemi-stry Ninth edition, Oxford University press, 2010, 1019.

S. Günes, H. Neugebauer, N. S. Sarici-ftci, Conjugated Polymer-Based Organic Solar Cells, Chem. Rev., Vol. 107 (2007) 1324−1338.

E. L. Tae, S. H. Lee, J. K. Lee, S. S. Yoo, E. J. Kang, K. B. Yoon, A Strategy To Increase the Efficiency of the Dye-Sensitized TiO2 Solar Cells Operated by Photoexcitation of Dye-to-TiO2 Charge-Transfer Bands, J. Phys. Chem. B, Vol. 109 (2005) 22513−22522.

M. R. Narayan, Dye sensitized solar cells based on natural photosensitizers, Renewable and Sustainable Energy Reviews, Vol. 16 (2012) 208– 215.

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Published

2017-12-12